A copper (I or II)/diethylphosphite catalytic system for base-free additive dimerization of alkynes
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Add time:07/30/2019 Source:sciencedirect.com
Copper (I) or copper (II) salts and oxides promote regioselective head-to-head additive dimerization of aromatic and aliphatic terminal alkynes in the presence a catalytic amount of diethylphosphite. The reaction proceeds under ambient conditions without any added base with the formation of 1,4-disubstituted 1,3-enynes with the E isomer as major product in good to excellent yields. A plausible mechanism for additive dimerization of terminal alkynes is proposed.
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