Chiral copper-catalyzed asymmetric monoarylation of vicinal diols with diaryliodonium salts
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Add time:08/01/2019 Source:sciencedirect.com
The copper-catalyzed enantioselective monoarylation of meso-1,2-diols by the use of diaryliodonium triflates as aryl sources has been developed. The chiral copper(II) complex catalyzed the asymmetric desymmetrization effectively to afford optically active β-aryloxy alcohols in moderate to high chemical yields and enantioselectivity.
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