Thermodynamic studies of 2-(5-bromo-2-pyridylazo)-5-diethylamino)phenol Cu(II), Co(II), Ni(II) and Zn(II) complexes
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Add time:07/29/2019 Source:sciencedirect.com
The metal–ligand mole ratios and the stability constants of the Cu(II), Co(II), Ni(II) and Zn(II) complexes at 2-(5-bromo-2-pyridylazo)-5-diethylamino)phenol were determined using a spectrophotometric method at different temperatures (20, 30, 40 and 50±0.1 °C) and ionic strengths (0.05, 0.1 and 0.2) in 30% (v/v) aqueous ethanol. Plots of thermodynamic stability constants at zero ionic strength (ln K°) versus T−1 gave linear curves; the ensuing complex formation (ΔH° and ΔS°) values calculated from these plots. The changes in free energy for each metal–ligand system were evaluated.
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