Vinylmetallics as ligands
-
Add time:07/29/2019 Source:sciencedirect.com
Complexes of the type, [(acac)Rh(ViSiR3)2] and [(acac)Rh(Vi2SiR2)], are readily prepared by displacement of ethylene from [(acac)Rh(C2H4)2]. The compounds, which are less reactive to air than similar carbon analogues, have been characterized by 1H and 13C NMR. The 13C NMR results suggest that the vinylsilane ligands function as better π-acceptors than do similar carbon analogues, and that dπpπ interactions between the silicon atom and the double bond are decreased upon coordination of the vinylsilane.
We also recommend Trading Suppliers and Manufacturers of Acetylacetonatobis(ethylene)rhodium(I) (cas 12082-47-2). Pls Click Website Link as below: cas 12082-47-2 suppliers
Prev:An EXAFS study of methyl-substituted BENZENE CHROMIUM TRICARBONYL (cas 12082-08-5) complexes
Next:Acetylacetonatobis(isocyanide)(tetracyanoethylene)rhodium and related complexes. Rotation of tetracyanoethylene) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Effective hydrogenation of carbon monoxide to ethylene glycol using rhodium-trialkylphosphine-nitrogen base catalyst: critical role of nitrogen base promoter in controlling selectivity08/01/2019
- Reaction of allylsilanes with diethylene(η5-indenyl)rhodium(I)07/31/2019
- Acetylacetonatobis(isocyanide)(tetracyanoethylene)rhodium and related complexes. Rotation of tetracyanoethylene07/30/2019
