Bis-cyclopentadienyl(methylcyclopentadienyl)N,N-dialkyldithiocarbamato Chloro zirconium(IV) compounds
-
Add time:07/31/2019 Source:sciencedirect.com
Zirconium(IV) N,N-dialkyldithiocarbamates of the type Cp2Zr(S2CNR2)Cl and (MeCp)2Zr(S2CNR2)Cl (R = Me, Et) have been prepared by reaction of dicyclopentadienyl zirconium(IV) dichloride and bismethylcyclopenadienyl zirconium(IV) dichloride with anhydrous sodium N,N-dialkyldithiocarbamates in refluxing dichloromethane. Molecular weight, conductance and infrared data demonstrate that these complexes are toohomeric nonelectrolytes in which the dithiocarbamate ligands are bidentate. Therefore, the zirconium(IV) atom may be assigned a coordination number 5. Proton nmr studies have also been carried out for these complexes.
We also recommend Trading Suppliers and Manufacturers of Bis(methylcyclopentadienyl)zirconium dichloride (cas 12109-71-6). Pls Click Website Link as below: cas 12109-71-6 suppliers
Prev:Synthesis and structure of an air-stable bis(isopropylcyclopentadienyl) zirconium perfluorooctanesulfonate and its catalyzed benzylation of 1,3-dicarbonyl derivatives with alcohols
Next:Synthesis, characterization and structure of carboxylate derivatives of bis(methylcyclopentadienyl)titanium(IV)) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Developing potentially useful organometallic Lewis acid catalysts: (η-cyclopentadienyl)zirconium trichloride derivatives08/06/2019
- Reactions of the metallocene dichlorides [M(Cp)2Cl2] (M = Zr, Hf) and [Ti(MeCp)2Cl2] with the pyridine-2,6-dicarboxylate(−2) ligand: Synthesis, spectroscopic characterization and X-ray structures of the products08/05/2019
- Preparation and characterisation of some stereochemically rigid 7-coordinate mono-methylcyclopentadienyl zirconium(IV) tris-N, N-dialkyl dithiocarbamate complexes08/04/2019
- Photolytic cyclopentadienyl ligand exchange between dicyclopentadienylzirconium dichloride and related systems.08/03/2019
- Bis(cyclopentadienyl) zirconium(IV) amides as possible precursors for low pressure CVD and plasma-enhanced ALD08/02/2019
- Synthesis, characterization and structure of carboxylate derivatives of bis(methylcyclopentadienyl)titanium(IV)08/01/2019
- Synthesis and structure of an air-stable bis(isopropylcyclopentadienyl) zirconium perfluorooctanesulfonate and its catalyzed benzylation of 1,3-dicarbonyl derivatives with alcohols07/30/2019
- Synthesis and structure of an air-stable μ2-hydroxy-bridged binuclear complex of bis(methylcyclopentadienyl)dizirconium(IV) perfluorooctanesulfonate and its application in Lewis acid-catalyzed reactions07/29/2019
