[4+2] Cycloaddition reactions of acenaphth [1,2−a]acenaphthylene

Add time:07/29/2019    Source:sciencedirect.com

Diels-Alder reactions of the annelated pentalene 2 lead to [4.3.3]propellanes. Various substituted anthracenes 3 and cyclopentadienes 5 are tested as diene components. 2 may be classified as a rather electron-rich dienophile.

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