Selenium dioxide oxidation of 3-methyl-4,5,6,7-TETRAFLUOROINDOLE (cas 16264-67-8)s: an efficient route to tetrafluoro analogs of 3-formyl and 3-acetoxymethylindole systems

Add time:07/30/2019    Source:sciencedirect.com

Selenium dioxide oxidations of 3-methyl-4,5,6,7-tetrafluoroindoles gave 3-formyl or 3-acetoxymethyltetrafluoroindoles in unexpectedly high selectivities, which turned out to serve as useful intermediates for the syntheses of tetrafluoro analogs of tryptophan, tryptamine and indole acetic acid.

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