Scandium trifluoromethanesulfonate (cas 144026-79-9)-catalyzed mild, efficient, and selective cleavage of acetates bearing a coordinative group

Add time:07/12/2019    Source:sciencedirect.com

Scandium trifluoromethanesulfonate is a useful Lewis acid catalyst for cleavage of acetates containing coordinative groups adjacent to the acetyl carbonyl. The reaction proceeds under weak acidic conditions at room temperature. Racemizable α-keto acyloxy compounds are deacetylated without racemization. Selective mono-deacetylation at the 10-position of paclitaxel has been achieved.

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