Electrical conductivity of layered transition-metal phosphorus trisulfide (cas 12165-69-4) crystals

Add time:08/07/2019    Source:sciencedirect.com

FePS3, VPS3 and V0.78PS3 crystals are found to have electrical conductivity higher than 10−5 S cm−1, while MnPS3, NiPS3 and ZnPS3 crystals lower than 10−9 S cm−1 at room temperature. The high conductivity of the former crystals is attributed to their mixed valency on the metal and/or the S and P sites, which has been revealed by x-ray photoelectron spectroscopy.

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