Deiodinative fluorination of alkyl iodide with p-iodotoluene difluoride

Add time:08/02/2019    Source:sciencedirect.com

Oxidative fluorination of alkyl iodides with p-iodotoluene difluoride (4) was carried out. In the presence of Et3N–4HF, the fluorination reaction of prim-alkyl iodides selectively took place at the iodine position under mild conditions to give the corresponding alkyl fluorides in good yields.

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