Hydrophilic platinum complexes of N-2-hydroxyethyl- and N,N-di(2-hydroxyethyl)-N′-benzoylthiourea ligands. Crystal and molecular structure of N,N-di(2-hydroxyethyl)-N′-benzoythiourea
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Add time:08/09/2019 Source:sciencedirect.com
The crystal and molecular structure of hydrophilic N,N-di(2-hydroxyethyl)-N′-benzoylthiourea (H3L4) has been determined. This ligand coordinates to Pt(II), Pd(II) and Ni(II) in a bidentate manner yielding essentially neutral complexes of the type cis-[Pt(H2L4)2]. By contrast, N-(2-hydroexyethyl)-N′-benzoylthiourea (H3L5) behaves like a monodentate thiourea ligand and reacts with Pt(II) to yield a mixture of cis and trans complexes of [Pt(H3L5)2Cl2]. The ( + )FAB mass spectrum of the latter complexes is also discussed.
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