Synthetic studies on maduropeptin chromophore 1. Construction of the aryl ether and attempted synthesis of the [7.3.0] bicyclic system
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Add time:08/07/2019 Source:sciencedirect.com
The aryl ether system of the maduropeptin chromophore artifact 1 was constructed via an aldol type condensation (7+6, Schemes 1 and 2, 7+19, Scheme 4), but attempted synthesis and ring closure of aldehyde 25 (Scheme 4) to afford the enediyne core of 1 failed.
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