Studies on the synthesis of the core structures of the antitumor agents neocarzinostatin, kedarcidin, C-1027 and maduropeptin
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Add time:08/08/2019 Source:sciencedirect.com
The bicyclo[7.3.0]dodecadiyne core structure of the antitumor agents neocarzinostatin, kedarcidin, C-1027 and maduropeptin can be readily constructed by an intramolecular aldol reaction to form the C-8C-9 bond only if the C-6,7 triple bond is complexed as its η2Co2(CO)6-acetylene adduct.
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