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  • Electrodeposition of indium on W and Cu electrodes in the deep eutectic solvent choline chloride-ethylene glycol (1:2)

  • Add time:08/09/2019    Source:sciencedirect.com

    A procedure for drying the deep eutectic solvent (DES) choline chloride - ethylene glycol, ChCl-EG (1:2), based on the use of molecular sieves has been developed, being the final water content of the electrolyte 145 ± 5 ppm. In this dried DES, the stability of InCl and InCl3 as well as the electrochemical behaviour of their solutions has been investigated using electrochemical techniques, X-ray diffraction analysis (XRD) and scanning electron microscopy (SEM). Experiments performed under a N2 atmosphere show that InCl3, dissolved in the rich chloride media as InClp3-p, is reduced on a tungsten electrode to indium metal via only one electrochemical step. Conversely, InCl undergoes the following disproportionation reaction when dissolved in the eutectic ChCl-EG (1:2)3InCls+p−3Cl−⇌2In0+InClp3−p

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