Phase transitions in some hexahalostannates(IV) as revealed by the pure quadrupole resonance of halogens

Add time:08/07/2019    Source:sciencedirect.com

The quadrupole resonance of halogens in potassium hexachlorostannate(IV), potassium hexabromostannate(IV), ammonium hexachlorostannate(IV), ammonium(d4) hexachlorostannate(IV), and ammonium hexabromostannate(IV) was observed over a wide range of temperature, and transition points were located. The nature of the phase transitions is discussed from the number of resonance lines, the continuity or discontinuity of resonance frequencies at the transition points, and the temperature coefficient of resonance frequencies.

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