Solvent effects on the absorption and emission spectra of novel (E)-4-((4-(heptyloxy)phenyl)diazenyl)benzyl (((9H-fluoren-9-yl)methoxy)carbonyl)-d

Add time:08/05/2019    Source:sciencedirect.com

Amino acid appended azobenzene hybrid has been synthesized (Fmoc-al-az) and its electronic absorbance and fluorescence spectra were recorded at room temperature in a series of polar and non-polar solvents. The ground state and excited state dipole moments were calculated using solvatochromic shift method. A DFT based study was also performed using- Gaussian09 program package. We have observed that the absorption spectra don't show sensitive behavior to the change in the polarity of the solvent, whereas a bathochromic shift was observed in the fluorescence spectra as we moved from non-polar to polar solvents indicating a π→π* transition. It was observed that the dipole moment in the excited state is much higher than the ground state, due to the amino acid containing hydrogen bond acceptor (OCO) and hydrogen bond donor (NH) in Fmoc-al-az increasing the reorientation tendency of the solvent molecule around the dye therefore enhancing the stabilization of the excited state which is attributed to the high polarity of the excited states. DFT level electronic structure calculations are also performed for a better molecular level understanding of the experimental observations. We obtained a good correlation between the theoretical studies and experimental results.

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