Synthesis, structures and photophysical properties of phosphorus-containing silver 3,5-bis(trifluoromethyl)pyrazolates

Add time:07/14/2019    Source:sciencedirect.com

Reaction of a trinuclear silver pyrazolate {[3,5-(CF3)2Pz]Ag}3 complex with tricyclohexylphosphine at different reagent ratios leads to the formation of heteroleptic dinuclear or tetranuclear complexes. According to the single crystal X-ray analysis of the dinuclear complex, hexane molecules are incorporated into the cavities formed as the result of supramolecular packing. Coordination of a phosphine ligand makes dinuclear silver pyrazolate to exhibit blue emission at room temperature.

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Next:Synthesis, structures, and properties of lantern-type dinuclear ruthenium(II,III) complexes cis-[Ru2{3,5-(CF3)2-pf}2(O2CMe)2Cl] and [Ru2{3,5-(CF3)2-pf}3(O2CMe)Cl], 3,5-(CF3)2-pf− = N,N′-bis[3,5-bis(trifluoromethyl)phenyl]formamidinate anion)