Infrared and Raman spectra of strontium and barium pimelates monohydrates

Add time:08/11/2019    Source:sciencedirect.com

The salts of dicarboxylic acids with alkaline earth metals are not very thoroughly studied and only a few such compounds are well known and characterized. In this work a detailed examination of the infrared spectra recorded at room temperature (RT) and at the liquid nitrogen boiling temperature (LNT) and Raman spectra (at room temperature) of the monohydrates of strontium and barium pimelates, [Sr(μ6-C7H10O4)(H2O)]n and [Ba(μ6-C7H10O4)(H2O)]n respectively, has been carried on. These isostructural salts are important nucleating agents for processing of isotactic polypropylene (iPP). The vibrational spectra of the two salts have been interpreted by using factor group analysis. For more correct and unequivocal interpretation of the vibrational spectra, samples containing partially and almost fully deuterated crystallization water have also been prepared and studied. The effect of the metal ion on the vibrations of the pimelic acid ion as well as the strength of the hydrogen bonds formed by the crystallization water molecule has been discussed.

We also recommend Trading Suppliers and Manufacturers of Barium(+2)cation (cas 12238-75-4). Pls Click Website Link as below: cas 12238-75-4 suppliers

Prev:Crystal growth, thermal expansion, pyroelectricity and vibrational spectroscopy of barium antimony tartrate, Ba[Sb2((+)C4H2O6)2]·3H2O
Next:Comparative effect of black, green, oolong, and white tea intake on weight gain and bile acid metabolism)