Total synthesis of the germacranolide (±)-Aristolactone (cas 6790-85-8) via [2,3] wittig ring contraction

Add time:07/12/2019    Source:sciencedirect.com

The total synthesis of (±)-aristolactone (15) is described wherein the key cyclodecenynol precursor 10 is prepared in over 90% yield via a highly regio and stereoselective [2,3] Wittig rearrangement of the 13-membered propargylic ether 9.

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