Stereoconvergent synthesis of C-9 to C-16 fragment of trienomycin based on the regioselective opening of γ-δ-poxy acrylates with Trimethylaluminium.
-
Add time:08/07/2019 Source:sciencedirect.com
The C-9 to C-16 fragment, a key intermediate for the synthesis of a 21 membered ansamycin antibiotic, Trienomycin has been synthesized, involving Sharpless asymmetric epoxidation and the key stereoselective methylation of γ-δ-epoxy acrylates by Trimethylaluminium.
We also recommend Trading Suppliers and Manufacturers of trienomycin C (cas 100662-00-8). Pls Click Website Link as below: cas 100662-00-8 suppliers
Prev:Novel models for correlation of Solubility constant and diffusivity of N2O in aqueous 1-dimethylamino-2-propanol
Next:Stereoselective synthesis of C-9 to C-14 segment, a key intermediate for the total synthesis of trienomycin and micotrienins.) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- A carbohydrate approach to polyol fragments of amphotericin and the trienomycin- and mycotrienin antibiotics08/10/2019
- Isolation and structure determination of (+)-trienomycin F. An endgame synthetic strategy for the trienomycin family of antitumor antibiotics08/09/2019
- Stereoselective synthesis of C-9 to C-14 segment, a key intermediate for the total synthesis of trienomycin and micotrienins.08/08/2019
