Studies of protection of self-assembled films by 2-mercapto-5-methyl-1,3,4-thiadiazole on iron surface in 0.1 M H2SO4 solutions

Add time:08/09/2019    Source:sciencedirect.com

The self-assembled (SA) film of 2-mercapto-5-methyl-1,3,4-thiadiazole on the cathodic (McMT) was prepared on iron surface. The film was characterized by electrochemical impedance spectroscopy (EIS), electrochemical polarization, X-ray photoelectron spectroscopy (XPS), energy dispersive X-ray spectroscopy (EDS) and scanning electron microscopy (SEM). The results showed that McMT molecules formed a stable film on iron surface, which effectively protected iron from corrosion. The protection efficiency of the McMT self-assembled film was then calculated. The highest protection efficiency of McMT on the iron surface was ∼95.0%. Quantum chemical calculations and molecular simulations were further applied to reveal the adsorption structure and explain the experimental results.

We also recommend Trading Suppliers and Manufacturers of 2-Mercapto imidazoline (cas 12261-94-8). Pls Click Website Link as below: cas 12261-94-8 suppliers

Prev:The effects of thioureido imidazoline and NaNO2 on passivation and pitting corrosion of X70 steel in acidic NaCl solution
Next:Relationship between imidazoline/guanidinium receptive sites and monoamine oxidase A and B)