Highly selective synthesis of Acetylferrocene (cas 1271-55-2) by acylation of ferrocene over zeolites
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Add time:08/10/2019 Source:sciencedirect.com
Zeolites with different structure and concentration of acid sites were investigated in a liquid phase acylation of ferrocene with acetic anhydride. It was found that the conversion of ferrocene increased in the order: medium pore zeolites < 1D large pore zeolites < 3D large pore zeolites. Zeolite SSZ-33 with interconnecting 10 and 12-membered rings exhibited a slightly lower conversion compared with mordenite. The increase in the conversion of ferrocene was observed with decreasing Si/Al ratio for the given zeolite structure. Both Broensted and Lewis acid sites contribute to the catalytic activity of zeolites in ferrocene acylation. Mono-acylated ferrocene (Acetylferrocene (cas 1271-55-2)) was synthesized by this reaction with almost 100% selectivity.
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