Absence of experimental evidence of a delta-shock in the system Phenetole (cas 103-73-1) and 4-tert-butylphenol on Zorbax 300SB-C18
-
Add time:08/14/2019 Source:sciencedirect.com
We investigate the system consisting of Phenetole (cas 103-73-1) (PNT) and 4-tert-butylphenol (TBP) in methanol–water (63:37 v:v) on a Zorbax 300SB-C18 column by characterising single component isotherms, by performing a large number of binary experiments of different types and by describing the experiments through simulations carried out using a novel, rather powerful competitive adsorption isotherm, that we call the generalized bi-Langmuir isotherm. This system is of great interest because it was previously reported to yield a new type of transition in nonlinear chromatography, the so-called delta-shock. Such transition had been discovered earlier through a theoretical analysis and confirmed by detailed simulations. The initial aim of this work was to reach a satisfactory agreement between delta-shock experiments and corresponding numerical simulations. In the course of this work however, a number of inconsistencies in the interpretation of the previous experimental results were highlighted and explained. This led to a new experimental campaign, which is reported here and has allowed to reach two important conclusions: (1) The binary system PNT–TBP mentioned above does not exhibit a delta-shock; the spike in the UV profile, which has previously been interpreted as an experimental evidence of the delta-shock, results from liquid–liquid phase separation within the chromatographic column. (2) The same system exhibits a rather peculiar behavior in breakthrough and displacement experiments, which could be well described using the generalized bi-Langmuir isotherm.
We also recommend Trading Suppliers and Manufacturers of Phenetole (cas 103-73-1). Pls Click Website Link as below: cas 103-73-1 suppliers
Prev:Conformation and laser-induced fluorescence spectroscopy of Phenetole (cas 103-73-1) in supersonic jet
Next:Densities and viscosities for binary mixtures of Phenetole (cas 103-73-1) with 1-pentanol, 1-hexanol, 1-heptanol, 1-octanol, 1-nonanol, and 1-decanol at different temperatures) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Densities and viscosities for binary mixtures of Phenetole (cas 103-73-1) with 1-pentanol, 1-hexanol, 1-heptanol, 1-octanol, 1-nonanol, and 1-decanol at different temperatures08/15/2019
- Conformation and laser-induced fluorescence spectroscopy of Phenetole (cas 103-73-1) in supersonic jet08/13/2019
- Densities, viscosities and volumetric properties of BF3·anisole and BF3·Phenetole (cas 103-73-1) complexes at T = (283.15 to 303.15)K08/12/2019
- Densities, ultrasonic speeds and refractive indices of Phenetole (cas 103-73-1) with N-methyl-2-pyrrolidone, N,N-dimethylformamide and tetrahydrofuran binary mixtures at different temperatures08/11/2019