Mercuration of ferrocenyl-p-tolyl sulfoxide and its conversion to 1,2-disubstituted ferrocenes
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Add time:08/14/2019 Source:sciencedirect.com
1-(p-Tolylsulfinyl)-2-(chloromercurio)ferrocene (2) was prepared by direct mercuration of ferrocenylsulfoxide (1). This reaction can be performed at room temperature in open air. Cross-coupling reactions of compound 2 and aryl halides especially aryl iodides resulted in 1,2-disubstituted ferrocene derivatives with moderate to good yields.
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