Structure of seven organic salts assembled from 2,6-diaminopyridine with monocarboxylic acids, dicarboxylic acids, and tetracarboxylic acids

Add time:07/12/2019    Source:sciencedirect.com

Studies concentrating on non-covalent interactions between the organic base of 2,6-diaminopyridine, and carboxylic acids have led to an increased understanding of the role 2,6-diaminopyridine in binding with carboxylic acid derivatives. Here anhydrous and hydrated multi-component organic acid-base salts of 2,6-diaminopyridine have been prepared with the carboxylic acids as nicotinic acid, o-chlorobenzoic acid, 1,3-benzodioxole-5-carboxylic acid, 3,5-dinitrosalicylic acid, 4-nitro-phthalic acid, 1,4-cyclohexanedicarboxylic acid, and butane-1,2,3,4-tetracarboxylic acid. The seven crystalline compounds were characterized by X-ray diffraction analysis, infrared (IR), melting point (mp), and elemental analysis. All structures adopted the hetero R22(8) supramolecular synthons. The supramolecular architectures bear extensive NH⋯N, OH⋯N, OH⋯O, NH⋯O, and CH⋯O associations as well as other nonbonding contacts as CHN, CH2O, π–π, C–π, O–π, Cl–π, ClO, and OO interactions. The role of weak and strong hydrogen bonding in the crystal packing is ascertained.

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