Oxidative copolymerization of vinyl monomers with fumarates☆

Add time:08/13/2019    Source:sciencedirect.com

The kinetic parameters of the oxidative copolymerization of styrene, butyl methacrylate and butyl acrylate with dibutyl fumarate have been found. The mechanism of the process is examined and the influence of the nature of the monomer on the length of the material chains of the polyperoxides formed is established. The special aspects of the course of oxidative polymerization in real systems based on oligoester maleates have been analysed. Recommendations are made to lessen oxygen inhibition of curing of oligomer-monomer composites.

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