Transition metal complexes of organothiophosphorous ligands V.Some aryl esters and amides of dithiophosphoric acid and their nickel(II) and cobalt(II and III)complexes☆

Add time:08/15/2019    Source:sciencedirect.com

Tetraphosphorous decasulfide reacted with phenoxyethanol, α and β-naphthol, ortho-toluidine, ortho-aminophenol and ortho-phenylenediamine to give aryl esters or amides of dithiophosphoric acids. These were used as ligands in the synthesis of some nickel(II) and cobalt(II and III) complexes. With para-toluidine only the amide (p-CH3C6H4NH)3PS was isolated.

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