Bis(isocyclam)dicopper(II) complexes with a linear methylene chain bridge

Add time:08/14/2019    Source:sciencedirect.com

New binucleating ligands, bis(isocyclam) with a linear methylene chain bridge, n-bicy (n = 2, 3, 4) and their copper(II) complexes, Cu2(n-bicy)(ClO4)4· xH2O and Cu2(n-bicy)(NCS)4·yH2O have been synthesized. The magnetic moments of these complexes were normal, but the presence of magnetic coupling between copper(II) ions were clearly demonstrated by the hyperfine structure in the ESR spectra.

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