Air oxidation of pollutants on cathodic [email protected] oxide/graphite felt under room condition

Add time:08/16/2019    Source:sciencedirect.com

Oxygen in air is an eco-friendly and economical oxidant, and catalytic air oxidation technology have a great potential to sustain effective wastewater treatment. Here we report a novel cathodic air oxidation process under the catalysis of a [email protected] oxide composite loaded on a porous graphite felt. Such a process demonstrates extensive and stable effectiveness in oxidizing a variety of dyes, pharmaceuticals and personal care products at high mineralization efficiencies under room condition. Mechanistic study indicates organic pollutants are oxidized by oxygen at cathodic [email protected] oxide/graphite felt through a non-free radical pathway, in which oxygen atom is transferred from oxygen molecule to organic molecules via lattice oxygen species in nickel oxide. The nickel oxide is reduced in the cathodic electric field, liberating and activating lattice oxygen species as the oxidizer of organic pollutants. Then, oxygen re-oxidizes nickel into nickel oxide to replenish lattice oxygen species. Such an oxygen activation pattern through nickel/nickel oxide redox cycle enables pollutant degradation at low energy cost, thus endowing the cathodic air oxidation process with a great potential in practical wastewater treatment.

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