Activation mechanism of lead ion in the flotation of STIBNITE (cas 1317-86-8)

Add time:08/17/2019    Source:sciencedirect.com

The flotation of stibnite with Pb2+ as an activator was examined with micro-flotation tests, inductively coupled plasma mass spectrometry (ICP-MS) experiments and density functional theory (DFT) calculations. It was found that at a pH of 6.5, the addition of Pb(NO3)2 notably improved the flotation efficiency of stibnite with butyl xanthate (BX). At a pH of 6.5, Pb2+ was the dominant species adsorbing at the stibnite surface. DFT calculations implied that Pb2+ could adsorb at five different sites on the stibnite surface. Furthermore, BX could adsorb onto the Pb sites at the Pb-activated surface and the Sb sites of the un-activated surface, while the adsorption of BX on the Pb-activated surface is more stable.Partial density of states (PDOS) analysis revealed that the poor overlapping between the S 3p orbital of BX and the Sb 5s orbital accounts for the weak interaction between BX and the un-activated surface. For the Pb-activated surface, the Pb 6p orbital and the S 3p orbital of BX were efficiently overlapped with each other, resulting in a relatively stronger interaction between BX and the activated surface. The DFT simulation provides a deep insight into the role of Pb2+ during the activation flotation of stibnite.

We also recommend Trading Suppliers and Manufacturers of STIBNITE (cas 1317-86-8). Pls Click Website Link as below: cas 1317-86-8 suppliers

Prev:Extracting antimony from high arsenic and gold-containing STIBNITE (cas 1317-86-8) ore using slurry electrolysis
Next:Effect of selected parameters on STIBNITE (cas 1317-86-8) concentrates leaching by ozone)