A study of chromium(III) chloride complexes using CHROMIUM-51 (cas 14392-02-0) as tracer☆
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Add time:08/23/2019 Source:sciencedirect.com
Evidence for the existence of the outer-sphere ion-pair Cr(H2O)63+.Cl− in aqueous solutions containing chromium(III) and chloride is presented. The stability constant for the formation of the species has been determined at different fixed temperatures for solutions of ionic strength 1 M maintained with perchloric acid. The formation constant at 40° of the inner-sphere complex Cr(H2O)5Cl2+ has also been derived. A solvent extraction method and 51Cr as tracer were used for the measurements.
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