Two red salts derived from yellow 4-cyano-1-methylpyridinium iodide: 1,1′,1″-trimethyl-4,4′,4″-(1,3,5-triazin-2,4,6-triyl)tripyridinium trisiodide and 4-cyano-1-methylpyridinium triiodide
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Add time:08/16/2019 Source:sciencedirect.com
Crystal structures of 1,1′,1″-trimethyl-4,4′,4″-(1,3,5-triazin-2,4,6-triyl)tripyridinium trisiodide (m.p. 383 °C) and 4-cyano-1-methylpyridinium triiodide (m.p. 118 °C) are described. These red salts were obtained unexpectedly from yellow 4-cyano-1-methylpyridinium iodide in either water or methanol solution in contact with insoluble heavy metal chlorides under ambient conditions. Neither compound is widely described in the chemical literature.
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