Total synthesis of (±)-SARKOMYCIN (cas 11031-48-4)

Add time:08/16/2019    Source:sciencedirect.com

The total synthesis of the anticancer agent (±)-sarkomycin 1 is described. Sarkomycin 1 was prepared from 2-phenylthiomethyl-cyclopent-2-en-1-one 5 in four steps in 13% yield. The key reaction was the 1,4-addition of nitromethane to the cyclopentenone 5.

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