A new synthesis of (±)-SARKOMYCIN (cas 11031-48-4) from a β-ketophosphonate

Add time:08/17/2019    Source:sciencedirect.com

The total synthesis of (±)-sarkomycin starting from diethyl 2-oxopropanephosphonate is reported. The key step in this synthesis includes the Horner-Wittig reaction of 2-diethoxy-phosphoryl-3-carboxy-cyclopentanone with formaldehyde

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