Preparation and reactions of rhodium complexes of some alkenyloxy and alkenylamino-benzylamines and related compounds: A comparison with catalytic reactions

Add time:08/16/2019    Source:sciencedirect.com

Reactions of several allyloxy- and allylamino-benzylamines and a benzamide with [Rh(CO)2Cl]2 give monodentate rhodium complexes which show no evidence of alkene coordination. Reaction of these and related compounds with HRh(CO)(PPh3)3 give products arising from double bond isomerisation followed by cyclisation or liberation of propene. The results are compared with rhodium-catalysed reactions of these substrates with H2/CO.

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