Dynamic 1H NMR spectroscopic study of the restricted SN rotation in aryl-N-(arylsulfonyl)-N-(triphenylphosphoranylidene)imidocarbamates
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Add time:08/17/2019 Source:sciencedirect.com
Dynamic 1H NMR (500 MHz) investigation of aryl-N-(arylsulfonyl)-N-(triphenylphosphoranylidene)imidocarbamates in CDCl3, CD3COCD3, and CD3OD at the temperature range of 183–298 K is reported. The observed free energy barriers (almost 12 kcal mol−1) are attributed to conformational isomerization about the NS bond and these barriers show very little solvent dependence.
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