First complex of the monoprotonated trioxodinitrate (cas 15435-67-3) anion: synthesis and characterization of [Hg2(HN2O3)2(NO3)2(Ph2PNHPPh2)2]

Add time:08/17/2019    Source:sciencedirect.com

The reaction of Hg(NO3)2·H2O with bis(diphenylphosphino)amine, Ph2PNHPPh2 (dppam), produces [Hg2(HN2O3)2(NO3)2(dppam)2] (1), which is the first complex containing the monoprotonated trioxodinitrate (cas 15435-67-3) anion. 1 has been fully characterized by an X-ray structure analysis, NMR spectroscopy (199Hg{1H}, 31P{1H}, 1H), FAB mass spectrometry, IR spectroscopy, elemental analysis and melting point. 1 is the unique example of a face-to-face complex of five-coordinate Hg(II) centres with dppam including the first structural characterization of a rare tautomer of the monoprotonated trioxodinitrate anion.

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