Research paperUltrafast photo-induced charge transfer of 1-naphthol (cas 1321-67-1) and 2-naphthol (cas 1321-67-1) to halocarbon solvents
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Add time:08/22/2019 Source:sciencedirect.com
We explore the fluorescence quenching of 1-naphthol and 2-naphthol in halocarbon solvents by using time-correlated single-photon-counting, femtosecond IR-spectroscopy and quantum chemistry computations. We find that halocarbon solvents facilitate a de-excitation mechanism via solute-solvent electron transfer. Decay rates are modulated by close contact interactions between the π-electronic structure of naphthols and halocarbon molecules in their first solvation shell. 1-naphthol exhibits faster decay rates than 2-naphthol due to closer interactions with the solvent.
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