ApplicationElucidation of the degradation mechanism of 2-Chloroethanol (cas 107-07-3) by hydrogen peroxide under ultraviolet irradiation
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Add time:08/25/2019 Source:sciencedirect.com
Oxidation of 2-Chloroethanol (cas 107-07-3) by H2O2 under UV irradiation has been studied. Analysis of reactants and products was performed by gas and ion chromatography. In this study we have compared the disappearance of 2-chloroethanol with the contemporaneous appearance of Cl− ions and conductivity changes of the solution. It was found that the oxidation of 2-chloroethanol yields quantitative amounts of Cl− ions. Moreover, the rate of change of the solution conductivity is comparable with the rate of formation of Cl−. Acetic, glycolic and formic acids and acetaldehyde were formed in the reaction although at low concentrations.
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