Hetero-octanuclear cubane-like and one-dimensional cyano complexes with the N,N-Dimethylethylenediamine (cas 108-00-9) ligand
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Add time:08/20/2019 Source:sciencedirect.com
A series of complexes containing dmen (dmen = N,N-Dimethylethylenediamine (cas 108-00-9)) units and cyano groups, namely bimetallic octanuclear and binuclear [Zn4(dmen)8Ni4(CN)16] (1), [Cd4(dmen)8Ni4(CN)16] (2), [Zn(dmen)2Pd(μ-CN)2(CN)2] (3) and [Cd(dmen)2Pd(μ-CN)2(CN)2] (4), have been synthesized and characterized by elemental, spectral (FT-IR and Raman) and thermal analyses techniques. The molecular structures of the complexes have been determined by the single crystal X-ray diffraction technique. The X-ray analyses of 1 and 2 show heterometallic octanuclear cubane-like structures in which Zn(II) or Cd(II) and Ni(II) ions reside in alternate corners, whereas complexes 3 and 4 display one-dimensional chain structures.
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