Polyfluorinated tetraoxacalixarenes and bicyclooxacalixarenes. Interaction of pentafluorobenzonitrile with Resorcinol (cas 108-46-3), orcinol and tetrafluoroResorcinol (cas 108-46-3)
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Add time:08/19/2019 Source:sciencedirect.com
Successive interaction of pentafluorobenzonitrile with resorcinol, orcinol and tetrafluororesorcinol in Et3N−CH3CN system gives fluorinated tetraoxacalix[4]arenes ABAB and ABAC type in a good yield. Further reaction of obtained products with new additional equivalent of tetrafluororesorcinol or orcinol leads to the formation of the fluorine-containing bicyclooxacalixarenes. The ESI-MS method shows the possibility of fluorinated tetraoxacalixarenes and bicyclooxacalixarenes complexes formation with metal cations.
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