Regular ArticleExcess volumes of (1-Bromobutane (cas 109-65-9) + each of several isomers of butanol) at the temperatures 298.15 K and 313.15 K

Add time:08/26/2019    Source:sciencedirect.com

From density measurements at the temperatures T = 298.15 K and 313.15 K, excess volumes of (1-bromobutane + each of several isomers of butanol) were calculated. VE s are positive over the entire range of composition, except for mixtures containing butan-1-ol at T = 298.15 K, for which VE s show slightly negative values for mixtures very rich in butan-1-ol. Excess molar volumes VEm for {xBr(CH2)3CH3 + (1 - x )C4H9OH} increase in the sequence: CH3(CH2)3OH < CH3CH(CH3)CH2OH < CH3CH2CH(OH)CH3 < CH3C(CH3)(OH)CH3.

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