C–Br bond fission mechanism of 1-Bromo-3-chloropropane (cas 109-70-6) at 234 and 265 nm
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Add time:08/19/2019 Source:sciencedirect.com
The photodissociation of 1-Bromo-3-chloropropane (cas 109-70-6) was studied at 234 and 265 nm using ion velocity imaging technique. Bromine fragments in this study were produced via direct dissociation of C–Br bond. The speed and angular distributions of Br∗ and Br were measured. The appearance of chlorine fragments at 234 nm was assigned to a secondary dissociation process. The contributions of three excited states: 1Q1, 3Q0 and 3Q1 were estimated at each wavelength. Comparing with previous results, the study reveals more details about the dynamics of molecules with multichromophores.
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