Electrochemical fluorination of N,N,N′,N′-tetramethylethylenediamine
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Add time:08/22/2019 Source:sciencedirect.com
The electrochemical fluorination of N,N,N′,N′-tetramethylethylenediamine was carried out in a modified Simons type cell using anhydrous hydrogen fluoride as a solvent. Effects of various experimental parameters like concentration of amine, temperature, and current density etc. were investigated. In addition to perfluoro-N,N,N′,N′-tetramethylethylenediamine, cyclic, cleavage, and partially fluorinated products were obtained and characterized by gas chromatography, IR spectroscopy, nuclear magnetic resonance and mass spectra. A plausible reaction pathway for the electrochemical fluorination of N,N,N′,N′-tetramethylethylenediamine has been proposed based on the products obtained.
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