Short CommunicationHydrodeoxygenation of vegetable oils to liquid alkane fuels over Ni/HZSM-5 catalysts: Methyl hexadecanoate (cas 112-39-0) as the model compound

Add time:08/20/2019    Source:sciencedirect.com

Ni/HZSM-5 catalysts with different Ni loadings were prepared by impregnation method, and their catalytic performance was evaluated in the hydrodeoxygenation (HDO) upgrading of the model reactant Methyl hexadecanoate (cas 112-39-0) (MHD) to liquid alkane fuels. The physicochemical properties of the catalysts were characterized by XRD, SEM, NH3-TPD, and BET. Ni loadings were obviously influenced by the acidity, and thus significantly affected their catalytic performance. Over 7 wt.% Ni/HZSM-5 catalyst, MHD conversion of more than 90% and total liquid C5–C16 hydrocarbon selectivity of 83% were obtained under the optimum reaction condition, possibly due to the synergistic effect of metal Ni and acid HZSM-5.

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