Decomposition of dioxiranes induced by dialkyl ethers
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Add time:08/28/2019 Source:sciencedirect.com
Simple dialkyl ethers (i.e, diethyl or dihexyl ether), in addition to undergo oxidative cleavage by reaction with methyl(trifluoromethyl)dioxirane or dimethyldioxirane, induce the decomposition of these oxidation reagents in a concentration dependent manner. The identification of compounds derived from reactions with species such as CH3. or CF3CO2. suggests that the above decomposition is a radical chain process.
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