Data ArticleEquilibrium data for the cross-metathesis of Methyl oleate (cas 112-62-9) with cinnamaldehyde
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Add time:08/20/2019 Source:sciencedirect.com
Here we present equilibrium data for the cross-metathesis of Methyl oleate (cas 112-62-9) (MO) with cinnamaldehyde (CA) obtained experimentally from liquid-phase catalytic tests conducted at 323 K. The reaction was carried out in batch reactors, using different reactant molar ratios and the 2nd generation Ru Hoveyda-Grubbs complex as catalyst. Reaction mixtures at the equilibrium were analyzed by gas chromatography. Equilibrium constants were determined by assuming unitary activity coefficients for a cinnamaldehyde/methyl oleate equimolar ratio, and the validity of that approximation was evaluated by calculating the equilibrium conversions for different reactant molar ratios.
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