Hydrodeoxygenation of Oleic acid (cas 112-80-1) and palmitic acid to hydrocarbon-like biofuel over unsupported Ni-Mo and Co-Mo sulfide catalysts
-
Add time:08/21/2019 Source:sciencedirect.com
Second generation biodiesel, so-called bio-hydrogenated diesel (BHD), can be produced from hydrotreatment of vegetable oils. The hydrogenation (HDO) of Oleic acid (cas 112-80-1) and palmitic acid as model compounds of palm oil over unsupported Ni-Mo and Co-Mo sulfide catalysts was performed in a Parr reactor to produce BHD. The effects of reaction parameters: temperature, hydrogen pressure and the atomic ratio of catalysts (Ni/(Ni + Mo) or Co/(Co + Mo)) on the conversion and product yields (mainly n-C15, n-C16, n-C17 and n-C18 hydrocarbons) were evaluated. The results show that the high pressure favored HDO pathway, while high temperature strongly affected the decarboxylation and decarbonylation pathways. At optimal conditions for oleic acid HDO, the efficient catalyst was NiMoS2 catalyst (Ni/(Ni + Mo) = 0.2) which gave high oleic acid conversion (100%), n-C18 selectivity (78.8%) and n-C18 yield (70.3%) whereas, for palmitic acid HDO, NiMoS2 catalyst (Ni/(Ni + Mo) = 0.2) also gave high palmitic acid conversion (95.2%), n-C16 selectivity (78.5%) and n-C16 yield (65.6%).
We also recommend Trading Suppliers and Manufacturers of Oleic acid (cas 112-80-1). Pls Click Website Link as below: cas 112-80-1 suppliers
Prev:Data ArticlePhysicochemical data of Oleic acid (cas 112-80-1)-poloxamer organogel for intravaginal voriconazole delivery
Next:Acidic chitosan membrane as an efficient catalyst for biodiesel production from Oleic acid (cas 112-80-1)) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Redox properties and human serum albumin binding of nitro-Oleic acid (cas 112-80-1)08/28/2019
- Research articleEnzymatic esterification of Oleic acid (cas 112-80-1) by Candida rugosa lipase immobilized onto biochar08/27/2019
- Underwater wettability of Oleic acid (cas 112-80-1) on TiO2 photocatalyst surface08/26/2019
- Development and thermal characteristics of a novel composite Oleic acid (cas 112-80-1) for cold storageDéveloppement et caractéristiques thermiques d’un nouvel acide oléique composite pour le stockage frigorifique☆08/25/2019
- Oleic acid (cas 112-80-1)-induced defective autolysosome shows impaired lipid degradation08/24/2019
- Esterification of Oleic acid (cas 112-80-1) to biodiesel catalyzed by a highly acidic carbonaceous catalyst08/23/2019
- Acidic chitosan membrane as an efficient catalyst for biodiesel production from Oleic acid (cas 112-80-1)08/22/2019
- Data ArticlePhysicochemical data of Oleic acid (cas 112-80-1)-poloxamer organogel for intravaginal voriconazole delivery08/20/2019
-
Health and Chemical more >