Bond cleavage in hydroxyl derivatives initiated by electron transfer: electroreduction of 9H,9’H-bifluorene-9,9’-diol
-
Add time:08/24/2019 Source:sciencedirect.com
Cyclic voltammetry, digital simulation and quantum chemical methods were applied to study the electroreduction mechanism of vicinal hydroxyl derivatives using 9H,9’H-bifluorene- 9,9’-diol as an example. Unlike the case of fluoren-9-ol, dissociation of the C9–C9’ bond rather than the C9–OH one occurs in radical anion of the substrate, similarly to that in radical cations formed upon oxidation of vicinal hydroxyl derivatives.
We also recommend Trading Suppliers and Manufacturers of H-9 (cas 116970-50-4). Pls Click Website Link as below: cas 116970-50-4 suppliers
Prev:Basic ResearchDifferential contribution of C5aR and C5b-9 pathways to renal thrombic microangiopathy and macrovascular thrombosis in mice carrying an atypical hemolytic syndrome–related factor H mutation
Next:CO substitution vs CSi cleavage in the reactions of [(μ-H)M3(CO)9(CCSiR3)] (M = Ru, R = Me, Ph; M = Os, R = Me) with tertiary phosphines: Experimental and theoretical studies) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- 9 - H-conjugation and Regressive Product08/29/2019
- H-9 (cas 116970-50-4)08/28/2019
- Reactions of the face-capped benzothiazolate-substituted clusters Os3(CO)9(μ3,η2-C7H3NSR)(μ-H) (R = H, Me) with PPh3: Kinetic formation of Os3(CO)9(PPh3)(μ,η2-C7H3NSR)(μ-H) and thermally induced ligand isomerization08/27/2019
- Short communicationEvolutionary studies on the betaretrovirus RERV-H in the Leporidae family reveal an endogenization in the ancestor of Oryctolagus, Bunolagus and Pentalagus at 9 million years ago08/26/2019
- CO substitution vs CSi cleavage in the reactions of [(μ-H)M3(CO)9(CCSiR3)] (M = Ru, R = Me, Ph; M = Os, R = Me) with tertiary phosphines: Experimental and theoretical studies08/25/2019
- Basic ResearchDifferential contribution of C5aR and C5b-9 pathways to renal thrombic microangiopathy and macrovascular thrombosis in mice carrying an atypical hemolytic syndrome–related factor H mutation08/23/2019
- ArticlesExtending thrombolysis to 4·5–9 h and wake-up stroke using perfusion imaging: a systematic review and meta-analysis of individual patient data08/22/2019
- Palladium catalyzed domino C-H activation strategy: An access to 9- fluorenones08/21/2019
