Formation and Rearrangement of Dithioxo- and Diselenoxophosphoranes Carrying Bulky 4-t-Butyl-2,6-bis(methoxyalkyl)phenyl Groups

Add time:08/22/2019    Source:sciencedirect.com

[4-t-Butyl-2,6-bis(1-methoxy-1-methylethyl)phenyl]phosphine, [4-t-butyl-2,6-bis(2-methoxy-1,1-dimethylethyl)phenyl]phosphine, and [4-t-butyl-2,6-bis(3-methoxy-1,1-dimethylpropyl)phenyl]phosphine were prepared and allowed to react with sulfur or selenium, to give heterocyclic compounds containing phosphorus–oxygen bond, via rearrangement of the methyl moiety of the methoxy group.

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